Athletic Bilbao ended Sevilla's unbeaten start in La Liga with a 3-1 victory at San Mames, while Eibar beat Real Sociedad 2-0.
Argentine international Gabriel Mercado bundled home the winner as Sevilla moved up to second in La Liga with a 1-0 win over rivals Real Betis.
Antoine Griezmann scored twice as Atletico Madrid beat Sporting Gijon 5-0 in La Liga on Saturday.
Valencia's wretched start to the campaign continued as they suffered a third straight La Liga defeat at home to Real Betis.
Jon Driscoll and Terry Gibson return for an in-depth take on all the action and major talking points in La Liga.
Atletico Madrid were held to a goalless draw by Leganes on Saturday, while Valencia lost to Eibar.
Fulham have made a bid in the region of £3.5m for Eibar forward Sergi Enrich, Sky sources understand.
The 21st season of live Spanish football on Sky Sports gets underway this weekend with over 300 games available throughout the campaign.
Transfer sagas, managerial changes, new faces, old problems - Guillem Balague previews the new La Liga season.
What was the best goal scored in La Liga this season? Watch 12 of the top strikes here and vote for your favourite...
Catch up with the action as Barcelona, Real Madrid and Atletico continued their battle for the title in La Liga.
Swansea have agreed a club record £15m transfer fee for Atletico Madrid striker Borja Baston, according to Sky sources.
Sporting Gijon moved out of the La Liga relegation zone with a 2-0 win over Eibar on Friday evening.
Atletico Madrid kept pace in the La Liga title race as Fernando Torres' goal secured a 1-0 victory over Athletic Bilbao.
Celta Vigo were held by Real Betis on Saturday, while Sporting Gijon ended Las Palmas' three-game winning streak.
Cristiano Ronaldo scored one and created two more as Real Madrid thumped Eibar 4-0 in La Liga on Saturday.
Scroll back to see how Real Madrid eased past Eibar in La Liga.
Roberto Soldado scored the winner as Villarreal came from behind to beat Eibar 2-1 on Sunday.
Borja Baston scored a late equaliser as Eibar denied Getafe a vital victory in their relegation battle in a 1-1 draw.
Iago Aspas scored a brilliant chip to give Celta Vigo a 1-0 win over Real Sociedad to boost the Galicians Europa League hopes.