Brazil striker Neymar will remain at Barcelona "for life", according to the club's technical director Roberto Fernandez.
Celta Vigo were held to a goalless draw by Getafe as Eduardo Berizzo's side missed out on the chance to go top of La Liga.
In his live Q&A, Sky Sports Guillem Balague said there is no interest from Barcelona in Liverpool's Philippe Coutinho.
Villarreal moved to the top of the Primera Division by beating Atletico Madrid 1-0, while Sevilla also won on Saturday.
Iago Aspas scored twice as Celta Vigo thrashed Spanish champions Barcelona 4-1 at Balaidos on Wednesday night.
Luis Enrique paid tribute to Celta Vigo after they ended Barcelona's perfect start to the season in spectacular style.
Former Liverpool striker Iago Aspas struck twice as unbeaten Celta Vigo shattered Barcelona's 100 per cent start with a 4-1 win.
Javier Mascherano admits the manner of Barcelona's 4-1 defeat by Celta Vigo in La Liga on Wednesday was "worrying".
Villarreal defeated Athletic Bilbao to remain joint-second with Real Madrid and Celta Vigo.
Former Liverpool forward Iago Aspas has had a fine start to the season back at Celta Vigo.
Raul Garcia enjoyed a dream debut as Athletic Bilbao eased to a morale-boosting first win in La Liga this season.
Roberto Soldado was denied a dream debut for Villarreal against Real Betis.
Jon Driscoll is joined by Terry Gibson to discuss the weekend's action, while Guillem Balague speaks with Arsenal's Mikel Arteta.
La Liga's back and we've wrapped up the best goals from the opening weekend.
Sky Sports will remain the home of La Liga for another three seasons thanks to a new broadcast agreement announced today.
Rafael Benitez's first El Clasico will be at the Bernabeu, with the return fixture taking place in Barcelona in April.
Celta Vigo have snapped up former Manchester City striker John Guidetti on a Bosman free transfer.
Sheffield Wednesday have confirmed the season-long loan signing of Alex Lopez from Celta Vigo.
Sevilla have signed Denmark midfielder Michael Krohn-Dehli on a two-year contract, the club have announced.
Valencia qualified for next season's Champions League after winning at Almeria, who were relegated along with Eibar.