Sevilla climbed into the top half of the La Liga table after beating nine-man Valencia 1-0 on Sunday.
Atletico Madrid moved up to second in La Liga after a 1-0 victory at Real Betis on Sunday, as Granada and Levante also claimed wins.
Neymar scored a fantastic individual goal as Barcelona warmed up for El Clasico with a 3-0 victory at home to Villarreal.
Relive all the action as Neymar scores twice, including a superb volley, to help Barcelona beat Villarreal 3-0.
Neymar? Sergio Ramos? Inaki Williams? Take a look at three potential La Liga goal of the season contenders from over the weekend.
Athletic Bilbao stretched their winning run to five games on Sunday, while Sporting Gijon suffered defeat at Atletico Madrid.
Atletico Madrid beat Valencia 2-1 on Sunday while David Moyes' Real Sociedad cruised past Levante 4-0.
Pablo Hernandez struck a late winner as Celta came from behind to win at Real Sociedad and move third in La Liga.
Barcelona and Real Madrid will start their Copa del Rey campaigns against third-tier clubs.
Villarreal remain the early pacesetters in La Liga despite suffering their first defeat of the season against neighbours Levante.
In his live Q&A, Sky Sports Guillem Balague said there is no interest from Barcelona in Liverpool's Philippe Coutinho.
Napoli made it three wins out of three for Italian sides in the Europa League on Thursday night with a 2-0 victory at Legia Warsaw.
How have Villarreal got to the top of La Liga? How will Lionel Messi's injury affect the title race? Guillem Balague has the answers...
Villarreal moved to the top of the Primera Division by beating Atletico Madrid 1-0, while Sevilla also won on Saturday.
Villarreal moved level with Real Madrid and Celta Vigo at the top of La Liga as they won 1-0 at Malaga in a late kick-off.
Villarreal defeated Athletic Bilbao to remain joint-second with Real Madrid and Celta Vigo.
Roberto Soldado admits his return to Spain has surpassed all his expectations after a nightmare spell in the Premier League.
Raul Garcia enjoyed a dream debut as Athletic Bilbao eased to a morale-boosting first win in La Liga this season.
Roberto Soldado grabbed a goal and two assists as Villarreal came from behind to beat Espanyol 3-1 in La Liga on Friday.
Jon Driscoll is joined by Terry Gibson to discuss the weekend's action, while Guillem Balague speaks with Arsenal's Mikel Arteta.