Borussia Dortmund appear to be the only side in the Bundesliga able to challenge Bayern Munich after they beat Stuttgart 4-1.
Zlatan Ibrahimovic helped PSG ease into the Champions League last 16, while Antoine Griezmann inspired Atletico Madrid.
Bayern Munich pulled eight points clear at the top of the Bundesliga with a 3-1 win over Schalke on Saturday.
Wolfsburg slipped 13 points behind Bundesliga leaders Bayern Munich as they were beaten 2-0 at Mainz on Saturday.
Chelsea Ladies' hopes of reaching the Women's Champions League quarter-finals were dealt a blow after a 2-1 defeat to Wolfsburg.
Real Madrid beat PSG 1-0 to qualify for the Champions League's last 16, while PSV, Benfica and Shakhtar also won on Tuesday.
Borussia Dortmund and Wolfsburg both made inroads into Bayern Munich's advantage at the top of the Bundesliga with wins on Saturday.
PSG and Real Madrid played out a 0-0 draw in the Champions League, while Juventus and Borussia Monchengladbach also drew.
Bayern Munich opened up a 10-point lead at the top of the Bundesliga with a 4-0 victory over Cologne.
Bayern Munich set a Bundesliga record for the best start to a season with their ninth consecutive victory, a 1-0 win over Werder Bremen.
Hertha Berlin and Ingolstadt took advantage of a slip by Wolfsburg to move into the top five of the Bundesliga on Saturday.
Juan Mata scored one and set up another as Manchester United came from behind to beat Wolfsburg 2-1 at Old Trafford.
Relive the action as Manchester United claimed their first Champions League win of the season with a 2-1 victory over Wolfsburg.
Louis van Gaal was pleased to see Man Utd beat Wolfsburg, but stressed there is still plenty of room for improvement.
Matt le Tissier has praised Juan Mata after his stunning display guided Man Utd to their first Champions League win of the season.
Wolfsburg's sale of Kevin De Bruyne was unavoidable, according to the club's director of sport Klaus Allofs.
Former Chelsea forward Andre Schurrle says he left because of a breakdown in his relationship with Jose Mourinho.
Robert Lewandowski carved his name in history with a double for Bayern Munich, while Schalke drew level with Dortmund.
Robert Lewandowski scored five goals in nine second-half minutes to give Bayern Munich a 5-1 win over Wolfsburg.
Robert Lewandowski was struggling to comprehend his feat of scoring five times in nine second-half minutes to help Bayern thrash Wolfsburg 5-1.