PSV had to settle for a point in their bid to close the gap on top two Feyenoord and Ajax after being held to a goalless draw at Roda JC.
PSV Eindhoven closed on the Eredivisie leaders with a 3-1 win over ADO Den Haag at Philips Stadion.
Ajax thumped NEC Nijmegen 5-0 as they tightened their grip on second place in the Eredivisie on Sunday.
PSV Eindhoven extended their unbeaten Eredivisie run to six games but were held to a 1-1 draw against FC Twente.
Feyenoord's lead at the top of the Eredivisie was cut to three points after a 2-2 draw at home to Heerenveen on Sunday.
Feyenoord grabbed a late winner to secure their perfect record and Ajax's winning run continued.
Davinson Sanchez and Kasper Dolberg both scored twice as Ajax beat Zwolle 5-1 while PSV won at Excelsior.
Eric Botteghin struck a late winner as Feyenoord maintained their perfect start to the Eredivisie season with a 1-0 win at PSV.
Luuk de Jong capped a 24-minute blitz as PSV stormed back to the top of the Eredivisie with a 4-1 win over NEC in Nijmegen.
Dirk Kuyt scored twice as Feyenoord came from behind against Excelsior to maintain their 100 per cent Eredivisie record.
Defending champions PSV Eindhoven defeated PEC Zwolle 4-0 to secure top spot in the Eredivisie.
Ajax were held to a draw by Roda JC in a four-goal thriller on Saturday, while Vitesse lost at home to ADO Den Haag.
Reagy Ofosu scored on his NEC Nijmegen debut to salvage a 1-1 draw against PEC Zwolle in the opening game of the Eredivisie season.
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PSV Eindhoven retained the Eredivisie title after a dramatic final day that saw Ajax slip up when it mattered most.
Ajax moved a step closer to reclaiming the Eredivisie title on Sunday with a thumping 4-0 win over FC Twente.
Ajax have returned to the top of the Eredivisie table after winning 2-0 away at Heerenveen.
PSV Eindhoven returned to the top of the Eredivisie table after a 3-0 success at Roda JC sealed a third straight win.
Eredivisie leaders PSV Eindhoven were held to a frustrating 1-1 draw by Heerenveen at Philips Stadion on Saturday.