Pablo Fornals' injury-time equaliser kept the relegation heat on Valencia as Malaga rescued a 2-2 draw at the Mestalla.
Valencia beat Leganes 3-1 in the first leg of their Copa del Rey fourth-round clash, while Espanyol came from behind to draw.
Barcelona begin their Copa del Rey defence against Hercules, while Real face a trip to Leon to take on Cultural y Deportiva Leonesa.
Real Sociedad beat Real Betis 1-0 in La Liga on Friday thanks to Carlos Vela's second-half goal.
Argentine international Gabriel Mercado bundled home the winner as Sevilla moved up to second in La Liga with a 1-0 win over rivals Real Betis.
Malaga battled back to secure a 2-2 draw away to Espanyol in La Liga on Friday evening, while Deportivo and Betis drew 0-0.
The 21st season of live Spanish football on Sky Sports gets underway this weekend with over 300 games available throughout the campaign.
Jon Driscoll and Terry Gibson return for an in-depth take on all the action and major talking points in La Liga.
Recap all the action as Leicester, Watford and Hull win pre-season friendlies and West Ham and Burnley draw.
The number of Madrid teams in La Liga dropped from four to two as Getafe and Rayo Vallecano were relegated on the final day.
What was the best goal scored in La Liga this season? Watch 12 of the top strikes here and vote for your favourite...
Gus Poyet has been unveiled as the new head coach of La Liga side Real Betis on a two-year deal.
Catch up with the action as Barcelona, Real Madrid and Atletico continued their battle for the title in La Liga.
Re-cap all the action as Barcelona travelled to Real Betis in La Liga.
Celta Vigo's European hopes were dealt a blow as they were held to a 1-1 draw by Espanyol.
Celta Vigo were held by Real Betis on Saturday, while Sporting Gijon ended Las Palmas' three-game winning streak.
Atletico Madrid tightened their grip on second spot in La Liga with a 5-1 win over Real Betis but Valencia lost again.
A stunning long range goal from Yevhen Konoplyanka inspired Sevilla to a 4-2 home win over Villarreal in La Liga.
Granada took a step towards survival by overcoming Sporting Gijon 2-0 at the Estadio Los Carmenes.
Roberto Soldado scored the only goal of the game as Villarreal kept their top-four hopes on track with a 1-0 win over Malaga.