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Ahead of the draw, Sky Sports looks at all of the 32 teams who have qualified for the 2014 World Cup.
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Ahead of the ceremony, we profile the contenders and focus on athlete Christine Ohuruogu.
|team 1||score||team 2|
|Romania||1 - 1||Greece|
Greece coach Otto Rehhagel had no complaints after seeing his side crash out of the World Cup following a 2-0 defeat to Argentina.
The 2004 European Champions adopted a cautious approach in the hope that a point would be enough for them to sneak through in second place in Group B.
But with South Korea drawing 2-2 with Nigeria, it was the Asian outfit who booked a meeting with Uruguay in the second round.
Argentina's victory came thanks to late goals from Martin Demichelis and veteran striker Martin Palermo and saw them top Group B with a maximum nine points.
Rehhagel admitted his side were second-best, but that was to be expected against Diego Maradona's star-studded side.
"It was a well-deserved victory, no doubt about that," said the 71-year-old German.
"We wanted to avoid an early goal, we managed to do that, but of course Argentina had more class and that earned them the win.
"My players played with their hearts and with excitement
"But it was just not enough to cause Argentina much trouble."World Cup. Click here to bet.
Bryan Swanson, Chief News Reporter for Sky Sports News, reflects on the FIFA press conference ahead of Friday's World Cup draw in Costa do Sauipe, Brazil.
It will be dramatic and it will be tense - right from the start.
England will learn their World Cup fate on Friday - and Sky Sports will bring you live coverage of the draw, both on television and online.
Read the thoughts and opinions of Jamie Carragher with skysports.com
Jose Holebas scored the winner as Greece beat Republic of Ireland 1-0 in Wednesday's friendly in Dublin.
Republic of Ireland welcome Greece to the Aviva Stadium in their first home game since the thrashing by Germany.
Greece climbed above opponents Slovakia into second spot in World Cup qualifying Group G with a narrow win in Bratislava.
Greece and Bosnia-Herzegovina maintained their unbeaten starts to World Cup qualifying Group G with a hard-fought goalless draw in Piraeus.
Second-half goals from Sotiris Ninis and Kostas Mitroglou gave Greece their second straight win in Group G with a 2-0 success over Lithuania.