Borja Baston salvaged a point for Alaves in a 1-1 draw at Girona on Saturday but the visitors missed the chance to move up to third place in La Liga table.
Barcelona moved five points clear at the top of La Liga after a battling 2-1 win over Getafe on Sunday.
Jonathan Calleri scored the only goal as Alaves climbed to fifth in La Liga with a 1-0 win at Real Sociedad, while Girona and Getafe drew 1-1 in the day's other game.
Leeds United forward Samuel Saiz has agreed to join Getafe on loan in January with a view to a permanent move.
Antoine Griezmann dragged Atletico Madrid level with Barcelona at the top of La Liga, scoring twice to beat Valladolid.
Iago Aspas scored twice as Celta Vigo got back on track in La Liga with a 2-0 victory over Huesca.
Sevilla took full advantage of Barcelona's draw with Atletico Madrid on Saturday to overtake both and go top of La Liga.
Diego Godin battled through injury to score a dramatic late winner as Atletico Madrid beat Athletic Bilbao 3-2 in La Liga on Saturday.
Alaves missed the chance to go second in La Liga after conceding an injury-time goal in a fiery 2-1 defeat to Basque rivals Eibar.
Surprise packages Alaves are second in La Liga after beating struggling Villarreal 2-1 on Sunday, while Sevilla also won.
Espanyol continued their rampant run of form by beating basement club Huesca 2-0 on Sunday to go second in La Liga.
Eibar ran out 3-2 winners at Girona in La Liga on Saturday, where there was an action-packed end to the first half.
Alaves missed the chance to join Barcelona and Real Madrid at the top of La Liga as Getafe held them 1-1 at Mendizorroza.
Thomas Lemar grabbed his first La Liga goal to help Atletico Madrid to a 2-0 win at Getafe.
Angel struck twice in the first half as Getafe claimed a 2-0 La Liga win over Sevilla in a compelling clash on Sunday.
Villarreal's difficult start to the La Liga season continued as they were beaten 1-0 at home by Girona on Friday.
Nabil El Zhar scored twice in the second half as Leganes battled back from two goals down to snatch a 2-2 draw against Real Sociedad.
Gareth Bale scored as Real Madrid made a winning start to the La Liga season with a 2-0 victory at home to Getafe on Sunday.
Spanish football captains will meet on Wednesday to discuss concerns over La Liga's plan to stage a league game in the US.
Crystal Palace have agreed a deal to sign goalkeeper Vicente Guaita from Getafe on a three-year contract.
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