Atletico Madrid edged out Deportivo with a 1-0 victory and Valencia came from behind to beat Leganes 2-1 in La Liga.
Atletico Madrid coach Diego Simeone had plenty to be unhappy about despite seeing his side move up to third with a 1-0 win over Deportivo.
A late goal from Las Palmas striker Sergio Araujo held Real Madrid to a 2-2 draw in La Liga on Saturday evening.
Cristiano Ronaldo was far from impressed after being substituted by Zinedine Zidane as Real Madrid drew at Las Palmas.
Barcelona dismissed 10-man Sporting Gijon in La Liga on Saturday, with Neymar scoring twice in a 5-0 victory.
Athletic Bilbao ended Sevilla's unbeaten start in La Liga with a 3-1 victory at San Mames, while Eibar beat Real Sociedad 2-0.
Barcelona coach Luis Enrique conceded the 5-0 scoreline flattered his side as they beat Sporting Gijon on Saturday afternoon.
Zinedine Zidane was left to rue a "cruel" setback after Real Madrid conceded a late equaliser to draw 2-2 with Las Palmas.
Barcelona stopper Marc-Andre ter Stegen appeared to handle outside the area during the win over Sporting Gijon - but escaped a booking.
Relive the action as Barcelona beat Sporting Gijon 5-0 in La Liga on Saturday afternoon.
Follow live updates as Las Palmas scored a late equaliser to hold Real Madrid to a -2 draw in La Liga on Saturday evening.
Barcelona have opposed the re-opening of Neymar's transfer case and denied claims of a Uruguay "pact" over Luis Suarez.
A Madrid court has re-opened a case into alleged irregularities regarding the transfer of Neymar to Barcelona.
Get the latest on Lionel Messi's injury from Guillem Balague, including whether the Barcelona star will be fit to face Man City...
Guillem Balague talks about Valencia's problems and potential candidates for the top job at the Mestalla, plus more.
Valencia claimed their first win of the season, while there were away victories for Espanyol and Leganes in La Liga on Thursday evening.
Real Madrid midfielder is facing a spell on the sidelines after tests confirmed he has suffered a broken leg.
Andres Iniesta says Pep Guardiola cannot persuade him to quit Barcelona, but insists his future is out of his hands.
Barcelona head coach Luis Enrique expects his team to adapt to Lionel Messi's absence when they face Sporting Gijon.
Barcelona were held to a 1-1 draw by Atletico Madrid on Wednesday in a game which saw Lionel Messi brought off with a groin injury.