Atletico Madrid moved up to second in La Liga after a 1-0 victory at Real Betis on Sunday, as Granada and Levante also claimed wins.
Valencia hit five to beat high-flying Celta Vigo, while Eibar continued their rise up La Liga with victory over Getafe.
Eibar maintained their top-six La Liga position after an own goal gave them a 1-0 victory over Rayo Vallecano.
Sevilla thrashed Getafe 5-0 in La Liga on Saturday night, while Granada drew with Real Betis and Malaga saw off Deportivo.
Barcelona and Real Madrid will start their Copa del Rey campaigns against third-tier clubs.
A hat-trick from Brazilian striker Charles saw Malaga beat David Moyes' Real Sociedad 3-1 and get off the winning mark this season.
In his live Q&A, Sky Sports Guillem Balague said there is no interest from Barcelona in Liverpool's Philippe Coutinho.
Valencia secured a much-needed 1-0 win over Granada in La Liga on Friday - their first home victory of the season.
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