Real Sociedad recovered from losing to Basque rivals Bilbao last weekend to see off Alaves in a 3-0 win on Saturday evening.
Barcelona begin their Copa del Rey defence against Hercules, while Real face a trip to Leon to take on Cultural y Deportiva Leonesa.
Real Sociedad beat Real Betis 1-0 in La Liga on Friday thanks to Carlos Vela's second-half goal.
Athletic Bilbao ended Sevilla's unbeaten start in La Liga with a 3-1 victory at San Mames, while Eibar beat Real Sociedad 2-0.
Las Palmas' impressive start to the campaign hit the skids in San Sebastian as they were torn apart 4-1 by Real Sociedad.
Jon Driscoll and Terry Gibson discuss the fallout from Cristiano Ronaldo’s substitution at the weekend, plus much more.
Villarreal secured a third consecutive win thanks to a goal of the season contender from Nicola Sansone in a 2-1 success at home to Real Sociedad.
Atletico Madrid were held to a goalless draw by Leganes on Saturday, while Valencia lost to Eibar.
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Red Bull Street Style World Final
8th November 2016