Fernando Torres was the fitting match-winner as Atletico Madrid waved goodbye to their Vicente Calderon stadium by beating Athletic Bilbao 3-1 on Sunday.
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Sevilla edged closer to sealing a Champions League place despite being pegged back by Real Sociedad in a 1-1 home draw.
Caretaker boss Tony Adams saw his Granada side relegated from La Liga after suffering a 2-1 defeat at Real Sociedad.
Osasuna's relegation was confirmed after Leganes thrashed Las Palmas 3-0 on Wednesday.
Willian Jose headed the winner as Real Sociedad boosted their Europa League hopes with a 1-0 success over Deportivo La Coruna.
Lionel Messi scored twice to help a tired Barcelona see off Real Sociedad 3-2 at the Nou Camp and close the gap on Real Madrid to three points.
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