Barcelona begin their Copa del Rey defence against Hercules, while Real face a trip to Leon to take on Cultural y Deportiva Leonesa.
Real Sociedad beat Real Betis 1-0 in La Liga on Friday thanks to Carlos Vela's second-half goal.
Argentine international Gabriel Mercado bundled home the winner as Sevilla moved up to second in La Liga with a 1-0 win over rivals Real Betis.
Malaga battled back to secure a 2-2 draw away to Espanyol in La Liga on Friday evening, while Deportivo and Betis drew 0-0.
The 21st season of live Spanish football on Sky Sports gets underway this weekend with over 300 games available throughout the campaign.
Jon Driscoll and Terry Gibson return for an in-depth take on all the action and major talking points in La Liga.
Recap all the action as Leicester, Watford and Hull win pre-season friendlies and West Ham and Burnley draw.
The number of Madrid teams in La Liga dropped from four to two as Getafe and Rayo Vallecano were relegated on the final day.
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Red Bull Street Style World Final
8th November 2016