Villarreal remain the early pacesetters in La Liga despite suffering their first defeat of the season against neighbours Levante.
In his live Q&A, Sky Sports Guillem Balague said there is no interest from Barcelona in Liverpool's Philippe Coutinho.
David Moyes' Real Sociedad were held to a 0-0 draw in the Basque derby by Athletic Bilbao, while Deportivo moved up to sixth.
Villarreal moved level with Real Madrid and Celta Vigo at the top of La Liga as they won 1-0 at Malaga in a late kick-off.
Leaders Barcelona maintained their 100 per cent start to the season by beating Levante 4-1 at the Nou Camp.
Recap Barcelona's 4-1 win over Levante as Lionel Messi scored, then missed, a penalty in a dramatic outing.
Roberto Soldado was denied a dream debut for Villarreal against Real Betis.
Why goalkeeper Keylor Navas has the quality to seize his unlikely chance at Real Madrid.
More of the games that matter on Sky Sports
A WEEK of Sky Sports. Only £6.99!
Exclusive interviews and pundit previews
All the gossip from the morning editions
Listen to the latest Premier League news