Shakhtar Donetsk maintained their 100 per cent start to Europa League Group H as they thrashed Gent 5-0.
Manchester City striker Nolito says he has Barcelona boss Luis Enrique to thank for propelling him to the top of the game.
Barcelona begin their Copa del Rey defence against Hercules, while Real face a trip to Leon to take on Cultural y Deportiva Leonesa.
Jon Driscoll is joined by special guest Rob Palmer to discuss Fabio Capello's recent remarks about Cristiano Ronaldo and Celta Vigo's new Chinese owners.
Barcelona missed the chance to go top of La Liga as they fell to a 4-3 defeat in a classic encounter at Celta Vigo.
Relive the action as Celta Vigo recorded a 4-3 win over Barcelona in a thrilliing La Liga encounter.
Three-time champions Inter Milan face a battle to get through Europa League Group K after a second successive defeat.
Las Palmas' impressive start to the campaign hit the skids in San Sebastian as they were torn apart 4-1 by Real Sociedad.
Villarreal secured a third consecutive win thanks to a goal of the season contender from Nicola Sansone in a 2-1 success at home to Real Sociedad.
Antoine Griezmann scored twice as Atletico Madrid won 4-0 at Celta Vigo in La Liga on Saturday, while Sevilla and Villarreal also claimed victories.
Jon Driscoll and Terry Gibson return for an in-depth take on all the action and major talking points in La Liga.
Italy international Giuseppe Rossi has joined Celta Vigo from Fiorentina.
Toni Kroos' late winner ensured Real Madrid maintained their perfect start to the new season with a 2-1 home victory over Celta Vigo.
Scroll back to see how Real Madrid edged Celta Vigo in La Liga.
Man Utd will face Fenerbahce, Feyenoord and Zorya Luhansk in the Europa League, while Southampton are in a group with Inter Milan.
Real Madrid coach Zinedine Zidane says his side have 'room for improvement' following a hard-fought 2-1 win over Celta Vigo.
Valencia started their La Liga season with a shock 4-2 home defeat to Las Palmas, as Shkodran Mustafi started on the bench.
The 21st season of live Spanish football on Sky Sports gets underway this weekend with over 300 games available throughout the campaign.
Manchester City have announced the signing of Spain international forward Nolito from Celta Vigo.
Celta Vigo forward Nolito could join Manchester City as early as this week, according to Sky sources.