Las Palmas' impressive start to the campaign hit the skids in San Sebastian as they were torn apart 4-1 by Real Sociedad.
Villarreal secured a third consecutive win thanks to a goal of the season contender from Nicola Sansone in a 2-1 success at home to Real Sociedad.
Antoine Griezmann scored twice as Atletico Madrid won 4-0 at Celta Vigo in La Liga on Saturday, while Sevilla and Villarreal also claimed victories.
Jon Driscoll and Terry Gibson return for an in-depth take on all the action and major talking points in La Liga.
Italy international Giuseppe Rossi has joined Celta Vigo from Fiorentina.
Toni Kroos' late winner ensured Real Madrid maintained their perfect start to the new season with a 2-1 home victory over Celta Vigo.
Scroll back to see how Real Madrid edged Celta Vigo in La Liga.
Man Utd will face Fenerbahce, Feyenoord and Zorya Luhansk in the Europa League, while Southampton are in a group with Inter Milan.
Real Madrid coach Zinedine Zidane says his side have 'room for improvement' following a hard-fought 2-1 win over Celta Vigo.
Valencia started their La Liga season with a shock 4-2 home defeat to Las Palmas, as Shkodran Mustafi started on the bench.
The 21st season of live Spanish football on Sky Sports gets underway this weekend with over 300 games available throughout the campaign.
Manchester City have announced the signing of Spain international forward Nolito from Celta Vigo.
Celta Vigo forward Nolito could join Manchester City as early as this week, according to Sky sources.
After Manchester City announced the signing of Nolito, we look at how the late developer could be utilised by Pep Guardiola.
Nolito is a summer transfer target for Manchester City, according to Sky sources, although no deal has been done yet.
Athletic Bilbao secured fifth place on the final day of the season in La Liga as they saw off nine-man Sevilla 3-1.
He’s not the biggest name in Spain's squad but Nolito could be a crucial figure at Euro 2016.
What was the best goal scored in La Liga this season? Watch 12 of the top strikes here and vote for your favourite...
Catch up with the action as Barcelona, Real Madrid and Atletico continued their battle for the title in La Liga.
Villarreal have secured qualification for next season's Champions League after a 2-0 victory at Valencia on Sunday.