Celta Vigo returned to the top four in La Liga on Saturday while Deportivo La Coruna extended their unbeaten run.
Real Sociedad pulled clear of the La Liga relegation zone with a 2-0 win over Sevilla.
Valencia hit five to beat high-flying Celta Vigo, while Eibar continued their rise up La Liga with victory over Getafe.
Atletico Madrid missed the chance to climb to the top of La Liga after drawing 1-1 with Deportivo on Friday night.
Atletico Madrid are ready to challenge for La Liga title this season, according to manager Diego Simeone.
Sevilla thrashed Getafe 5-0 in La Liga on Saturday night, while Granada drew with Real Betis and Malaga saw off Deportivo.
Barcelona and Real Madrid will start their Copa del Rey campaigns against third-tier clubs.
A hat-trick from Brazilian striker Charles saw Malaga beat David Moyes' Real Sociedad 3-1 and get off the winning mark this season.
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