Neymar was sent off as PSG moved 13 points clear at the top of Ligue 1 following a dramatic 4-3 win over Bordeaux.
Barcelona were made to work for their win against third-place Getafe in La Liga on Saturday while PSG were held 4-4 by Amiens in France.
Robert Lewandowski scored another double to send Bayern Munich through to the DFB-Pokal quarter-finals as Lazio missed the chance to go second in Serie A.
Eighteen-year-old Daniel Maldini, the son of AC Milan great Paolo, made his debut for the Rossoneri right at the end of a 1-1 draw with Hellas Verona.
Juventus' lead at the top of Serie A was cut to three points after they suffered a 2-1 defeat against Napoli.
Real Madrid moved top of La Liga, until Sunday evening at least, with a 2-1 win at Alaves while Bayern Munich were beaten by Bayer Leverkusen.
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