Lucas Moura's agents will meet with Napoli sporting director Cristiano Giuntoli on Wednesday, according to Sky in Italy.
Chinese Super League club Shandong Luneng Taishan are also showing strong interest in the 25-year-old Brazilian, whom Tottenham have been monitoring in the January window.
Moura has confirmed he is unhappy at the Parc des Princes after struggling to hold down a place in the first team this season.
PSG are understood to want to part with him permanently this month and are not keen on letting him out on loan.
Widespread reports claimed Manchester United were interested before they switched attention to signing Alexis Sanchez, while further reports this week say he is of interest to Arsenal.
Sky Sports News understands Arsenal are in talks to sign Borussia Dortmund's striker Pierre-Emerick Aubameyang.