Karim Benzema scored for the first time in a Madrid derby at the Bernabeu as Real Madrid beat Atletico Madrid 1-0.
Quique Setien suffered his first defeat as Barcelona boss as Valencia secured a 2-0 win to preserve their unbeaten La Liga home record this season.
Luis Suarez provided a goal and three assists as Barcelona opened up a three-point gap at the top of La Liga after a 4-1 victory over Alaves at Nou Camp.
Jadon Sancho scored for the seventh successive game before hobbling off injured as Borussia Dortmund drew 3-3 with Bundesliga leaders RB Leipzig.
Barcelona's six-game winning streak in all competitions was brought to an end as they were held to a 2-2 draw at Real Sociedad.
Bayern Munich hammered Borussia Dortmund 4-0 at the Allianz Arena, while Real Madrid also hit four against Eibar to keep up with the pace at the top of La Liga.
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