The former Liverpool forward scored twice during a 3-1 win over Athletic Bilbao to extend his season league tally to six - all scored in his last four games.
Real Madrid's Marco Asensio (No 5, up 48 places) stormed up the chart after hitting a wonder goal against Las Palmas, with Casemiro (No 28, up 44 places) opening the scoring and Isco (No 2, up three places) sealing the win.
Cristiano Ronaldo (No 61, down one place) has scored only one league goal so far this term, but assisted Isco's 74th-minute goal to retain his place just outside of the top 50 performers.
Lionel Messi (No 3, down one place) failed to cap his 600th appearance for Barcelona with a goal during a 2-1 victory over Sevilla at the Nou Camp.
Last week's table-topper Goncalo Guedes slipped three places to No 4, while Valencia team-mates Rodrigo (No 6, up seven places), 'keeper Neto (No 9, up two places) and Daniel Parejo (No 10, up 106 places) made the top 10.
Girona striker Cristhian Stuani (No 7, up 16 places) was back among the top performers, scoring his fourth goal in as many La Liga games during a 2-1 win at Levante.
Meanwhile, Real Sociedad youngster Mikel Oyarzabal (No 9, up two places) continued his impressive form, netting his sixth league goal of the season in a 3-1 win over Eibar.
Fernandinho & KDB top PL Power Rankings
Sky Sports Power Rankings: Man City's Fernandinho and Kevin De Bruyne top
The Power Rankings methodology reflects a player's performance over the last five matchdays by awarding points to players for 32 different stats.
Below, we present this week's Power Rankings, your club's top points scorer and the accumulative season rankings.
The Sky Sports Power Rankings will be updated every week during the season, so be sure to keep an eye on the big movers...