Bayern Munich inflicted more misery on Schalke as they left the Veltins-Arena with a 2-0 victory to cement first place in the Bundesliga.
Lionel Messi and Roberto Firmino starred in the opening round of Champions League group games, while Jadon Sancho made history.
Bayern Munich made it three wins from three under Niko Kovac in the Bundesliga with a 3-1 victory over Bayer Leverkusen.
Schalke paid the price for missing an early penalty as they suffered a second defeat of the Bundesliga season at home to Hertha Berlin.
Leon Goretzka scored his first goal for Bayern Munich as the defending Bundesliga champions won 3-0 at Stuttgart.
Cristiano Ronaldo is set for a return to Old Trafford after Juventus were drawn against Manchester United in the Champions League group stage.
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